I'm clueless when it comes to pop songs. Honestly though, if they can write an original song to the tune of the SUPERGIRL AND FLASH THEME, I'll cry. Actually cry.
Not really sure you could put words to their themes....especially Flash's theme, that would be a little weird. But definitely better be a duet with the two of them.
Kelly, Flash's theme is fast and soaring and would challenge the best of singers with lyrics. Supergirl's, roughly inspired by John WIlliams' Superman March almost sings out "Supergirl" in its inspiring tones, the same way WIlliams did with his song, and even Sammy Timberg for the 1940's cartoon shorts.
But I will go next level here. I'm wondering if Blake Neely could rearrange Supergirl's theme and give it a sort of dance beat. Believe it or not during the disco era in the late 1970's there WAS a Superman disco song based on John Williams' theme. And it's not that bad. It's performed by The Royal Band. You will have to go to YouTube for it. Of course, 40 years ago, a guy named Meco took another John Williams song, Star Wars and turned it into a #1 pop hit.